Organometal Fragment Substituted Silanols, Siloxanes and Silylamines

Iron‐Fragment‐Substituted Heterosiloxanes of Gallium [Cp(OC)2Fe−SiR2OGaR′2]2(R, R′ = Alkyl, Aryl) − Structures of [Cp(OC)2Fe−SiR2OGaMe2]2(R = Me, Ph)

“…In this paper we present the first examples of successful coupling reactions between metallo-silanols Cp(OC) 2 FeϪSi(R)(RЈ)OH (R ϭ RЈ ϭ Me, iPr, Ph; R ϭ Me, RЈ ϭ Ph) [13,14,21] and diverse trialkylgallanes. Moreover, we describe investigations concerning the influence of the transition metal fragment on the aggregation mode.…”