Organometallic Chemistry Control of Hydrogenases

Darensbourg, Marcetta Y.; Oduaran, Erica; Ding, Shengda; Lunsford, Allen M.; Pathirana, Kavindu Dilshan Kariyawasam; Ghosh, Pijush K.; Yang, Xuemei

doi:10.1007/978-3-030-58315-6_10

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Cited by 3 publications

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“…The CO ligand is also contained in NiFe and FeFe hydrogenase, and it maintains the low valence state of iron by the delocalization of pi electrons. 58 …”

Section: Resultsmentioning

confidence: 99%

H₂activation by hydrogenase-inspired NiFe catalyst using frustrated Lewis pair: effect of buffer and halide ion in the heterolytic H–H bond cleavage

2021

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“…The CO ligand is also contained in NiFe and FeFe hydrogenase, and it maintains the low valence state of iron by the delocalization of pi electrons. 58 …”

Section: Resultsmentioning

confidence: 99%

H₂activation by hydrogenase-inspired NiFe catalyst using frustrated Lewis pair: effect of buffer and halide ion in the heterolytic H–H bond cleavage

2021

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Carbon Dioxide Utilisation—The Formate Route

Maia

Moura

2020

Enzymes for Solving Humankind's Problems

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The relentless rise of atmospheric CO2 is causing large and unpredictable impacts on the Earth climate, due to the CO2 significant greenhouse effect, besides being responsible for the ocean acidification, with consequent huge impacts in our daily lives and in all forms of life. To stop spiral of destruction, we must actively reduce the CO2 emissions and develop new and more efficient “CO2 sinks”. We should be focused on the opportunities provided by exploiting this novel and huge carbon feedstock to produce de novo fuels and added-value compounds. The conversion of CO2 into formate offers key advantages for carbon recycling, and formate dehydrogenase (FDH) enzymes are at the centre of intense research, due to the “green” advantages the bioconversion can offer, namely substrate and product selectivity and specificity, in reactions run at ambient temperature and pressure and neutral pH. In this chapter, we describe the remarkable recent progress towards efficient and selective FDH-catalysed CO2 reduction to formate. We focus on the enzymes, discussing their structure and mechanism of action. Selected promising studies and successful proof of concepts of FDH-dependent CO2 reduction to formate and beyond are discussed, to highlight the power of FDHs and the challenges this CO2 bioconversion still faces.

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Polarized metal–metal multiple bonding and reactivity of phosphinoamide-bridged heterobimetallic group IV/cobalt compounds

Hunter,

Thomas

2024

Dalton Trans.

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Organometallic Chemistry Control of Hydrogenases

Cited by 3 publications

References 110 publications

H₂activation by hydrogenase-inspired NiFe catalyst using frustrated Lewis pair: effect of buffer and halide ion in the heterolytic H–H bond cleavage

H₂activation by hydrogenase-inspired NiFe catalyst using frustrated Lewis pair: effect of buffer and halide ion in the heterolytic H–H bond cleavage

Carbon Dioxide Utilisation—The Formate Route

Polarized metal–metal multiple bonding and reactivity of phosphinoamide-bridged heterobimetallic group IV/cobalt compounds

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Organometallic Chemistry Control of Hydrogenases

Cited by 3 publications

References 110 publications

H2activation by hydrogenase-inspired NiFe catalyst using frustrated Lewis pair: effect of buffer and halide ion in the heterolytic H–H bond cleavage

H2activation by hydrogenase-inspired NiFe catalyst using frustrated Lewis pair: effect of buffer and halide ion in the heterolytic H–H bond cleavage

Carbon Dioxide Utilisation—The Formate Route

Polarized metal–metal multiple bonding and reactivity of phosphinoamide-bridged heterobimetallic group IV/cobalt compounds

Contact Info

Product

Resources

About

H₂activation by hydrogenase-inspired NiFe catalyst using frustrated Lewis pair: effect of buffer and halide ion in the heterolytic H–H bond cleavage

H₂activation by hydrogenase-inspired NiFe catalyst using frustrated Lewis pair: effect of buffer and halide ion in the heterolytic H–H bond cleavage