Organometallic chemistry of bi- and poly-metallic complexes

The reaction of the ligand precursors P[CH2NHAr(R)]3 () with (Me2N)3Mo[triple bond, length as m-dash]N generated the complexes P(CH2NAr(R))3Mo[triple bond, length as m-dash]N (), where Ar(R) = 3,5-(CH3)2C6H3 (), Ph (), and 3,5-(CF3)2C6H3 (), with (Me2N)3Mo[triple bond, length as m-dash]N generated the complexes P(CH2NAr(R))3Mo[triple bond, length as m-dash]N (). Complex was obtained in poor yield, due to the formation of P(CH2N-3,5-(CF3)2C6H3)2(CH2NH-3,5-(CF3)2C6H3)(NMe2H)(NMe2)Mo[triple bond, length as m-dash]N () as the major product. Reaction of with VMes3THF generated the paramagnetic complexes P(CH2NAr(R))3Mo(μ-N)V(Mes)3 (). The reaction of with Ni(acac)2 generated the Ni(0) complexes Ni[P(CH2NAr(R))3Mo[triple bond, length as m-dash]N]4 () in poor yield. These complexes were synthesized in higher yields from the reaction of with Ni(COD)2, where COD = 1,5-cyclooctadiene. Reaction of either with V(Mes)3THF or with Ni(COD)2 generated the paramagnetic nonanuclear complex Ni[P(CH2NAr(R))3Mo(μ-N)VMes3]4 ().

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Reactions of rhodium carbonyl clusters with heterobidentate ligands. Synthesis and structural characterization of the Rh6(CO)15[(C6H5)2PC6H4N(CH3)2] and {Rh6(CO)15[(C6H5)2PC6H4NH(CH3)2]}[GaX4] cluster compounds

Gracheva

Linti²

2010

Russ J Gen Chem

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Organometallic chemistry of bi- and poly-metallic complexes

Cited by 3 publications

References 133 publications

ChemInform Abstract: Organometallic Chemistry of Bi‐ and Polymetallic Complexes

ChemInform Abstract: Organometallic Chemistry of Bi‐ and Polymetallic Complexes

Diamagnetic molybdenum nitride complexes supported by diligating tripodal triamido-phosphine ligands as precursors to paramagnetic phosphine donors

Reactions of rhodium carbonyl clusters with heterobidentate ligands. Synthesis and structural characterization of the Rh6(CO)15[(C6H5)2PC6H4N(CH3)2] and {Rh6(CO)15[(C6H5)2PC6H4NH(CH3)2]}[GaX4] cluster compounds

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