Organometallic Chemistry of Fluorinated Allenes

Lentz, Dieter; Nickelt, Natascha; Willemsen, Stefan

doi:10.1002/1521-3765(20020301)8:5<1205::aid-chem1205>3.0.co;2-g

Cited by 45 publications

(25 citation statements)

References 33 publications

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“…Several mononuclear complexes of 1,1-difluoroallene and tetrafluoroallene were prepared by ligand exchange reactions according to Scheme 2 [24,25].…”

Section: Coordination Compoundsmentioning

confidence: 99%

“…According to the spectroscopic data of 3, the allene is Z 3 coordinated to a Fe(CO) 3 moiety and Z 1 coordinated to a Fe(CO) 4 group and thus may be better regarded as a 2-ferraallyl ligand [25].…”

Section: Coordination Compoundsmentioning

confidence: 99%

“…On the attempt to coordinate 1,1-difluoroallene or tetrafluoroallene to cationic iron to force the coordination of the fluorine substituted site no allene complex could be isolated [25].…”

Section: Reactions Of the Allenes Within The Coordination Sphere Of Mmentioning

confidence: 99%

“…[25] However, cationic dicarbonyl(Z 5 -cyclopentadienyl)iron complexes of methyl substituted allenes could be prepared [28]. Obviously the cationic allene complexes which might be formed as intermediate species are stronger Lewis acids than boron trifluoride and abstract a fluoride ion from the anion BF 4 À forming s-bonded vinyl complexes.…”

Section: Reactions Of the Allenes Within The Coordination Sphere Of Mmentioning

confidence: 99%

“…tetrakis [3,5-bis(trifluoromethyl)phenyl]borate [29] to prevent the reaction of intermediate allene complexes with the anion, tetracarbonylbis(cyclopentadienyl)(m-iodo)diiron tetrakis- [3,5-bis(trifluoromethyl)phenyl]borate was the only isolated product [25]. Reaction of biscyclopentadienyldihydridomolybdenum with 1,1-difluoroallene gave low yields of a double hydrometallation product 9 besides other (Scheme 4) so far not identified air sensitive products.…”

Section: Reactions Of the Allenes Within The Coordination Sphere Of Mmentioning

confidence: 99%

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Organometallic chemistry of fluorinated propadienes and butadienes

Lentz¹

2004

Journal of Fluorine Chemistry

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“…Several mononuclear complexes of 1,1-difluoroallene and tetrafluoroallene were prepared by ligand exchange reactions according to Scheme 2 [24,25].…”

Section: Coordination Compoundsmentioning

confidence: 99%

Section: Coordination Compoundsmentioning

confidence: 99%

“…On the attempt to coordinate 1,1-difluoroallene or tetrafluoroallene to cationic iron to force the coordination of the fluorine substituted site no allene complex could be isolated [25].…”

Section: Reactions Of the Allenes Within The Coordination Sphere Of Mmentioning

confidence: 99%

Section: Reactions Of the Allenes Within The Coordination Sphere Of Mmentioning

confidence: 99%

Section: Reactions Of the Allenes Within The Coordination Sphere Of Mmentioning

confidence: 99%

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Organometallic chemistry of fluorinated propadienes and butadienes

Lentz¹

2004

Journal of Fluorine Chemistry

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Energetics of Organomanganese Compounds

Liebman

Slayden

2011

Patai's Chemistry of Functional Groups

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Diverse aspects of the energetics of organomanganese compounds are considered in this chapter. Bond energies, enthalpies of formation and enthalpies of reaction are discussed. Classical combustion calorimetry plays only a small role compared to reaction calorimetry and techniques from contemporary ion energetics. While carbonyl, cyano, cyclopentadienyl, and benzene derivatives dominate the discussion, species with numerous other σ and/or π‐bonded ligands also appear. Quantitation is given whenever possible.

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Mass Spectrometry and Gas‐Phase Ion Chemistry of Organomanganese Complexes

Palii

Zagorevskii

2011

Patai's Chemistry of Functional Groups

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This review (782 references) represents an exhaustive up‐to‐date survey of literature on mass spectrometry and gas‐phase ion chemistry of organomanganese complexes. Fundamental physico‐chemical characteristics of organomanganese ionic species, as well as the gas‐phase reactions resulting in the dissociation or formation of manganese‐carbon bond(s) are examined. Circa 300 examples of ion/molecule reactions characterizing the reactivity of Mn + , positively or negatively charged manganese clusters, as well as neutrals, cations and anions of various Mn‐containing species (including coordinatively unsaturated ones) are summarized. A variety of studies involving tandem mass spectrometry, neutralization‐reionization mass spectrometry, collision‐induced dissociation, multiple‐photon dissociation, IRMPD spectroscopy and theoretical calculations for organomanganese ion structure characterization are discussed. Additionally, analytical applications of mass spectrometric techniques to the characterization of compounds containing a MnC bond are reviewed. These include a number of relatively simple mononuclear complexes, polynuclear clusters, complexes incorporating organometallic units bridged with organic fragment(s), bifunctional compounds containing organometallic and classical Werner‐type coordination sites, fullerenes or planar polyaromatic hydrocarbons with an organomanganese fragment attached to them, manganospiralenes, manganoscorpionates, supramolecular entities, cymantrene‐peptide bioconjugates, etc.

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Organometallic Chemistry of Fluorinated Allenes

Cited by 45 publications

References 33 publications

Organometallic chemistry of fluorinated propadienes and butadienes

Organometallic chemistry of fluorinated propadienes and butadienes

Energetics of Organomanganese Compounds

Mass Spectrometry and Gas‐Phase Ion Chemistry of Organomanganese Complexes

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