Organometallic Fluorides:  Compounds Containing Carbon−Metal−Fluorine Fragments of d-Block Metals

Murphy, Eamonn F.; Murugavel, Ramaswamy; Roesky, Herbert W.

doi:10.1021/cr960365v

Cited by 289 publications

(182 citation statements)

References 242 publications

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“…These species were typically prepared by Cl/F exchange using AgF [17], or by C-F activation/hydrogenolysis of fluorinated alkenes [61]. Nowadays, the use of NEt 3 ·3HF is considered a more practical approach for metal fluoride synthesis [26,62].…”

Section: Rhodiummentioning

confidence: 99%

Transition metal bifluorides

Nahra

Brill

Gómez‐Herrera

et al. 2016

Coordination Chemistry Reviews

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A c c e p t e d M a n u s c r i p t HighlightsSince their discovery four decades ago, transition metal bifluoride complexes have long been considered as unwanted byproducts, a necessary evil, on the route to access fluoride complexes. Until recently, reports on this chemistry almost always presented these complexes as a fluke discovery. However, with the recent increase in reports and applications involving such species, a renewed interest in these complexes has been observed. Most of the work done in this area, so far, has been directed toward the synthesis and quite challenging characterization of these complexes, yet mostly neglecting the behavior of such species and their influence on catalytic processes. The aim of this work is to present a summary of the various preparation methods, characterization techniques and applications of reported transition metal bifluoride complexes. It is our hope that by centralizing all information available on such species, future efforts aimed at exploiting the full potential of transition metal bifluoride species can be facilitated.

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Section: Rhodiummentioning

confidence: 99%

Transition metal bifluorides

Nahra

Brill

Gómez‐Herrera

et al. 2016

Coordination Chemistry Reviews

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“…Fluoride is known to stabilize early-or middle-transition-metal complexes with fewer than six valence electrons by F 3 M p-donation [10], whereas the four-electron repulsion between the filled p-orbitals on the metal and the F p-orbitals is thought to account for the paucity of fluoro complexes of the late-transition-metal ions [15]. Interestingly, this interaction can be exploited to stabilize operationally unsaturated complexes with a formal 16-electron count [11] [15].…”

mentioning

confidence: 99%

Carbon−Fluorine Bond Formationvia a Five-Coordinate Fluoro Complex of Ruthenium(II), Preliminary Communication

Barthazy

Hintermann

Stoop

et al. 1999

HCA

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“…These authors [8] presented an extensive survey of M-F bond lengths and bond angles in the structures of organometallic fluorides. Organometallic fluorides of dblock metals, including Ti(IV), were also discussed by Murphy et al [9].…”

Section: Introductionmentioning

confidence: 96%