Organometallic Reactions of ι-Fluoroalkyl Halides. II.^1,2 Reactions of ι-Fluoroalkylmagnesium Chlorides

Abstract

1957-FLUOROALKYLMAGNESIUM CHLORIDES 161°. A mixture melting point "with an authentic specimen was not depressed.For a duplicate reaction 3.73 g. (88%) of triphenyl-2furyltin was recovered, melting at 159-160°.

Notes - Chloroalkyl and Chloroaryl Chloromethylphosphonates

“…This catalyst ivas used by Caprio and Shuman to prepare phosphates from chlorinated phenols. 3 The chloromethylphosphonates are insoluble in water but soluble in the common organic solvents. The chloromethylphosphonates derived from 2,2,2trichloroethanol and p-chlorophenol are white, crystalline solids.…”