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The origin of the recently discovered Flatreef remains debated due to the pronounced interaction of the magmatic rocks with sedimentary floor rocks, resulting in a complex intrusive stratigraphy. In this study, we report new Nd isotopic compositions of Flatreef lithologies intersected by borehole UMT-393 on the farm Macalacaskop in order to improve our understanding of the magmatic history of the deposit and to further test the putative correlation between the Flatreef/Platreef and the Upper Critical Zone of the remainder of the Bushveld Complex. The initial epsilon Nd (εNdi) values for the Flatreef range between −5.2 and −7.6, overlapping with εNdi values of the Upper Critical Zone from the eastern (ranging between − 4.8 and − 8.5) and the Upper Critical Zone and Main Zone from the western limb (−6.3 and −7.6, and −6.3 and −7.4 respectively) of the Bushveld Complex. The Flatreef εNdi values also overlap with those of the Platreef; however, due to the varying footwall lithologies of the Platreef along strike, Platreef rocks display a wider variation in isotopic composition. Our findings support the correlation of the Flatreef with the Upper Critical Zone — Main Zone transition interval in the remainder of the Bushveld Complex, which includes the Merensky and Bastard reefs. Due to significant overlap between the εNdi values of the Flatreef and local potential contaminants occurring at the base of the Northern Limb, we propose that the Sr–Nd isotopic composition of the magmas that gave rise to the Flatreef are most likely attributable to the interaction of mantle-derived magma with upper and lower crustal rocks of the Kaapvaal Craton within a sub-Bushveld staging chamber, with possible syn- to post-emplacement modification as a result of interaction with dolomitic footwall rocks.
The origin of the recently discovered Flatreef remains debated due to the pronounced interaction of the magmatic rocks with sedimentary floor rocks, resulting in a complex intrusive stratigraphy. In this study, we report new Nd isotopic compositions of Flatreef lithologies intersected by borehole UMT-393 on the farm Macalacaskop in order to improve our understanding of the magmatic history of the deposit and to further test the putative correlation between the Flatreef/Platreef and the Upper Critical Zone of the remainder of the Bushveld Complex. The initial epsilon Nd (εNdi) values for the Flatreef range between −5.2 and −7.6, overlapping with εNdi values of the Upper Critical Zone from the eastern (ranging between − 4.8 and − 8.5) and the Upper Critical Zone and Main Zone from the western limb (−6.3 and −7.6, and −6.3 and −7.4 respectively) of the Bushveld Complex. The Flatreef εNdi values also overlap with those of the Platreef; however, due to the varying footwall lithologies of the Platreef along strike, Platreef rocks display a wider variation in isotopic composition. Our findings support the correlation of the Flatreef with the Upper Critical Zone — Main Zone transition interval in the remainder of the Bushveld Complex, which includes the Merensky and Bastard reefs. Due to significant overlap between the εNdi values of the Flatreef and local potential contaminants occurring at the base of the Northern Limb, we propose that the Sr–Nd isotopic composition of the magmas that gave rise to the Flatreef are most likely attributable to the interaction of mantle-derived magma with upper and lower crustal rocks of the Kaapvaal Craton within a sub-Bushveld staging chamber, with possible syn- to post-emplacement modification as a result of interaction with dolomitic footwall rocks.
Giant mafic-ultramafic layered intrusions of Archaean-Proterozoic age are the fossilised remnants of huge injections of silicate magma in the Earth’s crust and are our most important repositories of platinum-group elements. Magmatic PGE-rich ore deposits, such as the Merensky Reef, are typically hosted in stratiform reefs at the contacts between ultramafic and feldspathic cumulates. The Merensky Reef is commonly characterised by coarse-grained and pegmatoidal textures that may provide important clues to its origin. We present textural and in situ geochemical data for Merensky pegmatoids at Styldrift Mine (Impala Bafokeng) in the Western Bushveld Complex of South Africa. This region is adjacent to an inferred magmatic feeder zone to the Bushveld. The Merensky pegmatoids are characterised by (i) amoeboid olivine inclusions in zoned orthopyroxene megacrysts with increasing molar Mg# of orthopyroxene towards olivine, (ii) fine-grained chains of orthopyroxene in compositional equilibrium with adjacent orthopyroxene megacrysts, (iii) increasing molar Mg# of orthopyroxene megacrysts and increasing molar An with decreasing 87Sr/86Sri (at 2.06 Ga) of plagioclase oikocrysts in pegmatoids laterally across a 10-km section distal to the feeder, and (iv) highly variable molar An and initial 87Sr/86Sri of interstitial plagioclase proximal to the feeder. We interpret the coarse-grained and pegmatoidal textures, their dissolution-reprecipitation features, and lateral chemical variations as the product of lateral melt infiltration and mixing in a crystal mush. We suggest that the platiniferous Merensky Reef was not formed at the base of a large melt-filled magma chamber but was instead the product of non-sequential magma emplacement that rejuvenated the crystal mush.
The Pyroxenite Marker, a thin, orthopyroxene-dominated marker horizon, is observed towards the top of the Main Zone of the Bushveld Complex, where the last voluminous influx of magma into the Bushveld Complex is thought to have occurred. In an attempt to constrain the Nd-isotopic composition of the magma added at the level of the Pyroxenite Marker, a total of 21 whole-rock samples from a borehole (BH7771) drilled on the Central Sector of the Eastern Limb of the Bushveld Complex were analysed for their Sr–Nd isotopic ratios. Modelling suggests that the added magma had a unique Sr (87Sr/86Sri = 0.7063–0.7067) and Nd (ƐNdi on the order of − 5.9) isotopic composition, distinct from any of the rocks constituting the layered sequence below the Pyroxenite Marker. Dispersion of data points around the modelled isotopic (melt–melt) mixing curves is interpreted to reflect the incorporation of minerals derived from either the incoming or resident magmas into individual rock layers occurring across the Pyroxenite Marker interval, either in response to the mixing of minerals settling through a stratified magma column, or potentially through the intrusion and mixing of crystal-laden magmas with unique isotopic compositions from a sub-Bushveld staging chamber.
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