PACS 73.40. Qv, 85.30.Tv We report on AlGaN/GaN metal-oxide-semiconductor heterostructure field-effect transistors (MOSHFETs) with MOCVD deposited Al 2 O 3 as a gate oxide. Properties of MOSHFETs with 9 nm and 14 nm thick Al 2 O 3 are compared with conventional HFETs prepared simultaneously on the same layer structure. Lower gate leakage current (~10 −5 A/mm at −10 V) and higher saturated drain current (up to 40 %) are obtained for MOSHFETs than those for HFETs. In contradiction to previously reported data, the extrinsic transconductance for MOSHFETs is also higher (up to 37% of peak values) than that for HFET. This indicates on semi-conductive rather than insulating properties of Al 2 O 3 gate oxide. Pulsed I−V measurements (pulse width 1 µs) yielded lower but still measurable current collapse in MOSHFETs compared to HFETs. Nevertheless, obtained results show that Al 2 O 3 gate oxide, after optimising its microstructure and thickness, can be preferable for the preparation of AlGaN/GaN MOSHFETs. 1 Introduction The GaN-based heterostructure field-effect transistors (HFETs) offer superior characteristics in terms of high-frequency output power, breakdown field and operating temperature when compared with GaAs-based HFETs. Recently, there is a growing interest in exploring AlGaN/GaN metal-oxide-semiconductor HFETs (MOSHFETs) because of lower gate leakage currents as well as possible application of high positive gate voltages thereby increasing voltage swing. In the first studies on AlGaN/GaN MOSHFETs, SiO 2 [1] and SiN [2, 3] were chosen as a good candidate for the gate dielectric applications. SiN was originally proposed as the passivation layer of AlGaN/GaN HFETs, i.e. to reduce their current collapse, and a density of interface states about ten times lower than that for SiO 2 was found [4]. However, the current collapse problem is not mitigated sufficiently using these two types of a gate dielectric [5]. This is the main reason that another, novel type, dielectrics such as AlN, MgO, Al 2 O 3 , ZrO, Sc 2 O 3 , Ga 2 O 3 , HfO 2 , Gd 2 O 3 are under study [6---9], and references therein]. However, the preference of a gate dielectric type has not been defined yet. Moreover, significantly better device performance was recently observed if a semi-conducting layer was used instead of highly insulating one [10]. Thin layer of Al 2 O 3 might fulfil well requirements on a gate material for GaN-based devices. The dielectric constant of Al 2 O 3 is larger than that of SiN and SiO 2 , ε = 8−10, its breakdown filed is high, E br > 10 MV/cm, and Al 2 O 3 can be prepared in different crystalline forms by various deposition techniques. Oxidation of thin MBE grown Al layer [11], sputtering [12] and plasma enhanced atomic layer deposition [13] were used to prepare AlGaN/GaN MOSHFETs with Al 2 O 3 as a gate oxide. Unfortunately, current collapse evaluation and large-signal rf measurements are not reported yet.