2024
DOI: 10.1021/jacs.4c05193
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Origin of Reactivity Trends of an Elusive Metathesis Intermediate from NMR Chemical Shift Analysis of Surrogate Analogues

Yuya Kakiuchi,
Scott R. Docherty,
Zachariah J. Berkson
et al.

Abstract: Olefin metathesis has become an efficient tool in synthetic organic chemistry to build carbon−carbon bonds, thanks to the development of Grubbs-and Schrock-type catalysts. Olefin coordination, a key and often rate-determining elementary step for d 0 Schrock-type catalysts, has been rarely explored due to the lack of accessible relevant molecular analogues. Herein, we present a fully characterized surrogate of this key olefin-coordination intermediate, namely, a cationic d 0 tungsten oxo-methylidene complex bea… Show more

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