To represent a comprehensive scenario regarding the coal mining and coal-fired power plant activities in a developing country (Bangladesh) and to understand the total environmental impacts, potential coal resources of Bangladesh, environmental geochemistry and dispersion of pollutants, eco-toxicological impacts, human health risks as well as socioeconomic impacts are evaluated in this chapter. Potential coal reserves along with the future plants are estimated. Technogenic sources of environmental pollutants including environmentally toxic heavy metals, health hazardous radionuclides, persistent organic pollutants, suspended particulate maters, etc. are assessed. In doing so, scarce associated data from coal mine (Barapukuria, Bangladesh) and Barapukuria coal-fired power plant (BTPP) of Bangladesh have been reconciled by using and arguing the previous works around the globe. Immense and proper literature reviews as well as the existing data on Barapukuria coal mine and BTPP are tabulated to compare and understand the condition along with the potential prevention and remediation approaches.