We study Birkhoff-James orthogonality of bounded linear operators on complex Banach spaces and obtain a complete characterization of the same. By means of introducing new definitions, we illustrate that it is possible in the complex case, to develop a study of orthogonality of bounded (compact) linear operators, analogous to the real case. Furthermore, earlier operator theoretic characterizations of Birkhoff-James orthogonality in the real case, can be obtained as simple corollaries to our present study. In fact, we obtain more than one equivalent characterizations of Birkhoff-James orthogonality of compact linear operators in the complex case, in order to distinguish the complex case from the real case. We also study the left symmetric linear operators on complex two-dimensional lp spaces. We prove that T is a left symmetric linear operator on ℓ 2 p (C) if and only if T is the zero operator.2010 Mathematics Subject Classification. Primary 46B20, Secondary 47L05. 1 2 KALLOL PAUL, DEBMALYA SAIN, ARPITA MAL AND KALIDAS MANDALLet X, Y be complex Banach spaces. Let B X = {x ∈ X : x ≤ 1} and S X = {x ∈ X : x = 1} be the unit ball and the unit sphere of X, respectively. Let L(X, Y)(K(X, Y)) denote the Banach space of all bounded (compact) linear operators from X to Y, endowed with the usual operator norm. We write L(X, Y) = L(X) and K(X,For any two elements x, y ∈ X, x is said to be B-J orthogonal to y, written asSimilarly, for any two elements T, A ∈ L(X), T is said to be B-J orthogonal to A, written asFor a linear operator T defined on a Banach space X, let M T denote the collection of all unit vectors in X at which T attains norm, i.e,