Mercury (Hg) is a unique metal with multiple oxidation states (0, +1, and +2) and physical states (solid, liquid, and gas) in nature. It has seven natural stable isotopes (196, 198-202, 204 amu), which undergo unique mass-dependent fractionation (MDF, expressed as δ 202 Hg) and mass-independent fractionation (MIF, typically expressed as Δ 199 Hg). Hg-MDF ubiquitously is generated during physical, chemical, biological processes, Hg-MIF is formed mainly during photochemical reactions with little influence from other processes (Blum et al., 2014). Past studies have utilized Hg isotopes to constrain anthropogenic Hg pollution sources (Kwon et al., 2020) and large volcanic Hg emissions in geological history (Grasby et al., 2019;Shen et al., 2020Shen et al., , 2022. The development of Hg isotopes for metallogenetic and petrogenetic tracing is progressing. Recent estimates on 3 He-rich basalts imply the lack of Hg-MIF signals in the primitive mantle (Δ 199 Hg = 0 ± 0.1‰; Moynier et al., 2021). Photochemical reactions have resulted in positive Δ 199 Hg values in marine sediments (0 to +0.4‰;