Oscillatory Changes in Structural Characteristics in Multicomponent Ceramics, YBCO

Abstract

Abstract. The structural characteristics of samples of a four-component superconducting material (YBCO) after exposure to X-ray irradiation during a long time are investigated. The effect of X-ray beam processing on angular positions (corresponding parameters of the crystal lattice) and the width of Bragg reflections is established. The phenomenon of oscillatory behavior in the unit cell dimension with long-time irradiation is found. The analysis of the profiles of reflection also demonstrates the presence of reversible changes phase composition with the exposure time. The observed phenomena reflect the presence of a nontrivial and specific process of compression and expansion of the unit cell due to the accumulation and then disengagement outside of ionized oxygen, which is formed under such irradiation exposure on the surface of the samples.