2022
DOI: 10.1002/zaac.202200013
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Osmium(IV) pyrophosphate: Synthesis, Crystallization, and Ligand‐Field Analysis of the [OsIVO6] Chromophore

Abstract: Dedicated to Professor Caroline Röhr on her anniversaryTwo polymorphs of burgundy-red OsP 2 O 7 , with cubic (ZrP 2 O 7 structure type, Z = 4, a = 7.8276(4) Å, 3 × 3 × 3 superstructure with a' = 3a = 23.484(2) Å) and triclinic symmetry (ruby-red crystals, single-crystal X-ray structure determination, GeP 2 O 7 structure type, P � 1 (no. 2), Z = 2, a = 4.8072(7) Å, b = 6.8993(13) Å, c = 8.050(1) Å, α = 91.82(2)°, β = 92.92(1)°, γ = 107.42(2)°, 98 parameters, R 1 = 0.045, wR 2 = 0.144, 3006 unique reflections wi… Show more

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