Simultaneous wireless information and power transfer (SWIPT) technology provides an efficient solution to energy-limited communication terminals in a wireless network. However, in the current application scenario of SWIPT technology, relays use all the collected energy forwarding to assist communication between source nodes, while ignoring the fact that relays can accumulate and store energy. This is of great practical significance in collaborative communication. By using a transmission scheme of a time-division broadcast for the direct transmission link, improvement of the system diversity gain through combining the technology at the receiver can be realized. Based on the above, we propose a two-way relay energy accumulation communication system, which is extended from a single relay system to a multi-relay system. The instantaneous transmission rate of the system link and the system equivalent profit are optimized by jointly optimizing the relay selection, time slot allocation factor, power splitting factor and relay transmit power. Compared with the comparison algorithm, the proposed algorithm shows a significant improvement in the performance of the system.