Constraining the surface environment of the early Earth is essential for understanding the origin and evolution of life. The release of cations from silicate weathering depends on climatic temperature and pCO 2 , and such cations sequester CO 2 into carbonate minerals in or on the seafloor, providing a stabilizing feedback on climate. Previous studies have suggested that this carbonate-silicate cycle can keep the early Earth's surface temperature moderate by increasing pCO 2 to compensate for the faint young Sun. However, the Hadean Earth experienced a high meteorite impactor flux, which produced ejecta that is easily weathered by carbonic acid. In this study, we estimated the histories of surface temperature and ocean pH during the Hadean and early Archean using a new model that includes the weathering of impact ejecta, empirically justified seafloor weathering, and ocean carbonate chemistry. We find that relatively low pCO 2 and surface temperatures are probable during the Hadean, for example, at 4.3 Ga, log 10 (pCO 2 ) (in bar) is −2.21 +3.01 −2.54 [2 ] and temperature is 259.2 +84.1 −14.4 [2 ] K. Such a low pCO 2 would result in a circumneutral to basic pH of seawater, for example, 7.90 +1.21 −1.69 [2 ] at 4.3 Ga.A probably cold and alkaline marine environment is associated with a high impact flux. Hence, if there was an interval of an enhanced impact flux, that is, Late Heavy Bombardment, similar conditions may have existed in the early Archean. Therefore, if the origin of life occurred in the Hadean, life likely emerged in a cold global environment and probably spread into an alkaline ocean.
Plain Language SummaryThe Earth's environment during the Hadean eon, 4.5 to 4 billion years ago, is obscured by a lack of geological evidence. However, life likely arose then, so improving our knowledge of the early environment is essential for understanding the origin and evolution of life. Here, we build a geological carbon cycle model that simulates the early surface environment and generates probability distributions for the level of atmospheric carbon dioxide (CO 2 ), average surface temperature, and ocean pH over time. During the Hadean, CO 2 dissolved in water is consumed by reacting with material ejected from meteorite impacts, so CO 2 levels tend to be low and the greenhouse effect weak. The consequences are low surface temperature and alkaline seawater. The probability that the surface temperature was lower than the freezing point of water and that seawater pH exceeded 7 is 70% at 4.3 billion years ago. Thus, if life began in the Hadean, it likely emerged in a cold global environment, and early life may have spread into an alkaline ocean.
Key Points:• We estimate the range of pCO 2 , surface temperature, and ocean pH in the Hadean and Archean • A cold, Hadean surface environment and circumneutral to basic ocean pH is likely because of impact ejecta weathering • The origin of life may have occurred in a cold environment, and early life may have spread into a cold alkaline ocean Supporting Information:• Supporti...