seamlessly. Therefore, electronic tattoo (E-tattoo) stickers with ultrathin, lightweight, and skin-adhesive electronics on top can be suitable candidates. In addition, self-powered electronics enable the untethered operation of on-skin E-tattoos and thereby expand their application range.Various self-powered E-skins with sensing applications based on piezoelectricity, [11][12][13] piezoresistivity, [14,15] capacitance, [16,17] and triboelectricity [18][19][20] have been reported. Triboelectricity, which is a physical phenomenon based on contactinduced electrification, is promising owing to the high electrical conversion efficiency for external stimuli such as mechanical vibrations, [21][22][23] sound, [24,25] wind, [26,27] water drops, [28,29] and contact with skin. [30,31] Unlike other physical mechanism-based E-skins that require complicated structures with multielectrode and thick substrates, [14][15][16] singleelectrode-based triboelectric devices are suitable build-up, self-powered, and skin-compatible sensors for next-generation HMIs because of their simplicity, broad material choice, and easy access. Zhao et al. presented a user-interactive self-powered E-skin based on the single-electrode triboelectric-optical model for touch operation. [32] Peng et al. presented a breathable, biodegradable, and self-powered E-skin with polymer nanofibers sandwiched between silver nanowire electrodes for the monitoring of electrophysiological signals and whole-body movements. [33] In addition, wearable flexible patches on selfpowered sensing platforms for robotics control and touch sensors have been presented. [34] However, achieving a conformal interface between the reported triboelectric-based E-skins [32][33][34][35][36][37] on the skin is difficult because some substrate materials are not biocompatible and the adhesive tapes used for measurements can cause irritation. Therefore, biocompatible, lightweight, ultrathin, on-skin stretchable, and self-powered E-tattoos are necessary for the untethered and imperceptible integration of electronics on human skin. Silk protein, a natural biopolymer, has been attracted much interest to realize self-powered E-tattoos with the aforementioned essential features, because of its tunable structural and mechanical properties and ease to functionalize or dope with other conductive materials. [38,39] In this paper, skin-compatible, ultrathin, lightweight, deformable, and biocompatible self-powered sensory E-tattoos based Triboelectric electronic skins (E-skins) can be used as primary interactive devices for human-machine interfaces (HMIs). However, devices for seamless on-skin operations must be soft and deformable, and attachable to and compatible with the skin. In this paper, a substrate-free, skin-compatible, skin-attachable, mechanically deformable, and self-powered E-tattoo sticker consisting of carbon nanotubes (CNTs) and silk nanofibers (SNFs) is presented. The E-tattoo can be imperceptibly tattooed on the skin and removed with water. When the device touches naked skin, triboelec...