“…27,28 TeO 2 has three basic structural units (see Figure 2), each containing an LPE: TeO 4 , trigonal bipyramid (tbp): Composed of 4 oxygen atoms that are linked by covalent bonds with the central atom of Te and form the tbp; TeO 4 , trigonal pyramid (tp): When Te-O bonds are broken, trigonal pyramids are created, where two sites are bridging oxygen (BO) and one nonbridging oxygen (NBO), which is a Te=O double bond and a distorted tbp with TeO 3+1 : it is the distortion of the tbp due to the presence of excess oxygen (δ). 29,30 Tellurite glasses offer a unique combination of a wide transparency range, high rare-earth solubility, low melting temperature, and chemical stability, making them an attractive choice for applications in optics and photonics. Table 2…”