2019
DOI: 10.1109/tdei.2019.008003
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Overheating decomposition characteristics of epoxy dielectrics in SF6 atmosphere

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Cited by 12 publications
(5 citation statements)
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“…As a result, H2O molecules could be released and react with SF6, this reaction develops the thermal decomposition of SF6. In addition, the organic insulating materials attract F atoms from SF6, resulting in low fluorine by-products [42][43] [44]. In a decreasing order of the quantity produced in the thermally induced reaction, or partial overheating fault (POF), are SO2, SOF2, SOF4, SO2F2, and H2S.…”
Section: Sf6 Decomposition By Thermal Effectmentioning
confidence: 99%
See 1 more Smart Citation
“…As a result, H2O molecules could be released and react with SF6, this reaction develops the thermal decomposition of SF6. In addition, the organic insulating materials attract F atoms from SF6, resulting in low fluorine by-products [42][43] [44]. In a decreasing order of the quantity produced in the thermally induced reaction, or partial overheating fault (POF), are SO2, SOF2, SOF4, SO2F2, and H2S.…”
Section: Sf6 Decomposition By Thermal Effectmentioning
confidence: 99%
“…The concentration of SOF4 and SO2F2 was minimal, and H2S was detected at temperatures above 340 °C. Furthermore, due to the above effect of organic insulating materials under overheating, decomposition of solid insulating materials has also been investigated under varied temperatures [42] [43]. Results had revealed that at 250°C, only H2, CO, CO2, and CH4 can be detected.…”
Section: Sf6 Decomposition By Thermal Effectmentioning
confidence: 99%
“…[2][3][4][5] However, EP primarily comprises carbon, hydrogen, and oxygen constituents, rendering it intrinsically prone to ammability, which restricts its potential applications. [6][7][8][9] To solve this problem, ame retardants can be added to the EP matrix to mitigate these combustion-related concerns effectively. Based on chemical composition and mechanism of action, ame retardants can be categorized into organic ame retardants and inorganic ame retardants.…”
Section: Introductionmentioning
confidence: 99%
“…2–5 However, EP primarily comprises carbon, hydrogen, and oxygen constituents, rendering it intrinsically prone to flammability, which restricts its potential applications. 6–9…”
Section: Introductionmentioning
confidence: 99%
“…Due to the diversity of complex compositions and extremely low concentrations (10 −9 -10 −6 ) of SF 6 decomposed products, the measurement instruments require high selectivity and sensitivity. Gas chromatography (GC) [6,7] coupled with pulsed discharge helium ionisation discharge detector (PDHID) or mass spectrometry (MS) is the current state of the art for SF 6 decomposition analysis with ppb-level sensitivity, high selectivity, and quantification accuracy. However, GC has several drawbacks for time-resolved and on-site applications: it requires different chromatography columns for the separation of sulfides and carbides, is time-consuming, expensive, difficult to calibrate, and limited in miniaturisation.…”
Section: Introductionmentioning
confidence: 99%