Supercritical carbon dioxide (SCO2) is widely used in many fields of energy and power engineering, such as nuclear reactors, solar thermal power generation systems, and refrigeration systems. In practical applications, SCO2 undergoes a cooling process significantly when it is cooled near the pseudo−critical point. Because of the drastic variations in thermo−physical properties, the heat transfer characteristics fluctuate, affecting the heat exchange and overall cycle performance. This paper summarizes extensive experiments and numerical simulations on the cooling process of SCO2 in various application scenarios. The effects of various working conditions, such as mass flow, working pressure, pipe diameter, flow direction, and channel shapes, are reviewed. The applicability and computational results using different numerical methods under different working conditions are also summarized. Furthermore, empirical correlations obtained in experiments at different conditions are included. The present review can provide a helpful guideline for the design of effective cooling systems or condensers so that the accuracy of the design and efficiency of the system can be improved.