This is the first
study that focuses on the evaluation of a newly
discovered oil shale deposit in the eastern Chenor area in the state
of Pahang, Malaysia. Previously, this deposit was reported as carbonaceous/coaly
mudstone. However, in this study, organic-rich immature carbonaceous
mudstone containing above 15 wt % total organic carbon (TOC) is evaluated
as oil shale, and that below 3.5 wt % TOC is termed mudstone. Oil
shale and mudstone, which are significant sedimentary facies for oil
and gas exploration, were investigated using organic geochemical and
petrological methods, as well as computed tomography (Micro-CT), pyrolysis,
and bulk kinetic techniques, to evaluate their hydrocarbon generation
potential. The vitrinite reflectance values are less than 0.5% R
o in all of the analyzed samples, indicating
low maturity stage. This is corroborated by T
max values ranging from 383 to 429 °C. However, based
on the kinetic simulation model, the average predicted geological
temperature for the onset of hydrocarbon generation is 109 °C,
while the peak of hydrocarbon generation is 153 °C. The extractable
organic matter and hydrocarbon contents results show that the oil
shale samples possess excellent petroleum potential compared to very
good values for the studied mudstone. This is consistent with the
plots of TOC content versus extractable organic matter, and hydrocarbon
yields versus TOC content, commonly used in estimating the hydrocarbon
generative potential of source rocks. The TOC of these oil shales
is consistent with that of the Tertiary oil shale deposits in China.
The analyzed oil shale samples are characterized by a high hydrogen
index (HI) of up to 700 mg HC/g TOC (average 517.4 mg HC/g TOC), suggesting
oil-prone type I and type II kerogens. However, the open pyrolysis-gas
chromatography (Py-GC) result of these samples displays a predominance
of n-alkene/n-alkane doublets extending
to the long-range homologous series (C7–C33) with considerably high aromatic compounds, which indicates type
II/III kerogens’ (mixed oil and gas) generative potential.
Similarly, bulk kinetic analysis of the analyzed samples suggests
typical petroleum source rock facies derived from heterogeneous (type
II/III kerogens) organic matter assemblages. Thus, based on the pyrolysis
and bulk kinetic result, the studied oil shale can be classified as
“‘cannel coal”’ derived from terrestrial
plants materials. This is supported by organic petrological and Micro-CT
studies which revealed that the samples are composed mainly of liptinite
(sporinite, cutinite, amorphous organic matter, and resinite) and
vitrinite, with varied trace amounts of inertinite.