Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate

Abstract

In the asymmetric unit of the title compound, [Mn(C2O4)(C3H10N2)2]Cl·H2O, there are two independent MnIII complexes, two Cl− anions and two uncoordinated water molecules. Each MnIII atom is hexacoordinated by four N atoms from two propane-1,3-diamine ligands and two O atoms from one oxalate ligand, resulting in a slightly distorted octahedral MnO2N4 geometry. Mn—O and Mn—N bond lengths are in the ranges 1.969 (2)–2.020 (3) and 2.068 (3)–2.113 (4) Å, respectively. There are weak intermolecular O—H...O, O—H...Cl, N—H...O and N—H...Cl hydrogen bonds with D...A distances in the range 2.831 (4)–3.423 (3) Å

μ-Oxido-bis{chlorido[tris(2-pyridylmethyl)amine]manganese(III)} bis(hexafluoridophosphate)

“…-Oxido-bis({4,4 0 -dibromo-2,2 0 -[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}chromium(III)) Liu, Dou, Niu & Zhang (2007b) 10.1107/S1600536807057996 HIQFIX -Oxido-bis{chlorido[tris(2-pyridylmethyl)amine]chromium(III)} bis(hexafluoridophosphate) 10.1107/S1600536807061296 MIRNAD -Oxido-bis({4,4 0 -dibromo-2,2 0 -ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}iron(III)) Meng et al (2008a) 10.1107/S1600536807063143 MIRWUG catena-Poly [[bis(1H-benzimidazole-N 3 )palladium(II)]--benzene-1,4-dicarboxylato-2 O 1 :O 4 ] Meng et al (2008b) 10.1107/S1600536807065051 XISCAE Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate Meng et al (2008e) 10.1107/S1600536807065361 SISWIB -Oxido-bis{chlorido[tris(2-pyridylmethyl)amine]manganese(III)} bis(hexafluoridophosphate) Meng et al (2008c) 10.1107/S1600536807066512 RISRIV Bis [N-(8-quinolyl)pyridine-2-carboxamidato-3 N,N 0 ,N 00 ]manganese(III) perchlorate monohydrate Meng et al (2008d) 10.1107/S1600536808000287 GISLEA Diaquabis(pyridine-2-carboxylato-2 N,O)cobalt(II) Huang (2008) 10.1107/S1600536808010507 WIZPOL Tetra--2,5-difluorobenzoato-bis[(2,2 0 -bipyridine)(2,5-difluorobenzoato)gadolinium(III)] 10.1107/S1600536808023507 et al (2008) 10.1107/S1600536808028389 NOHYUF catena-Poly[[aqua(2,2 0 -bipyridyl)cobalt(II)]--5-nitroisophthlalato] Liu et al (2008) 10.1107/S1600536808038178 AFIREN Diaquabis(pyridine-2-carboxylato-2 N,O)iron(II) Xia & Sun (2009) 10.1107/S1600536809005765…”

μ-Oxido-bis({4,4′-dibromo-2,2′-ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}iron(III))

“…-Oxido-bis({4,4 0 -dibromo-2,2 0 -[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}manganese(III)) Liu, Dou, Niu & Zhang (2007a) 10.1107/S1600536807051008 GIMZAE Bis[N-(8-quinolyl)pyridine-2-carboxamidato]iron(III) perchlorate monohydrate Li, Wang, Zhang & Yu (2007d) 10.1107/S1600536807048556 WIMZIC -Oxido-bis({4,4 0 -dibromo-2,2 0 -[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}chromium(III)) Liu, Dou, Niu & Zhang (2007b) 10.1107/S1600536807057996 HIQFIX -Oxido-bis{chlorido[tris(2-pyridylmethyl)amine]chromium(III)} bis(hexafluoridophosphate) 10.1107/S1600536807061296 MIRNAD -Oxido-bis({4,4 0 -dibromo-2,2 0 -ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}iron(III)) Meng et al (2008a) 10.1107/S1600536807063143 MIRWUG catena-Poly [[bis(1H-benzimidazole-N 3 )palladium(II)]--benzene-1,4-dicarboxylato-2 O 1 :O 4 ] Meng et al (2008b) 10.1107/S1600536807065051 XISCAE Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate Meng et al (2008e) 10.1107/S1600536807065361 SISWIB -Oxido-bis{chlorido[tris(2-pyridylmethyl)amine]manganese(III)} bis(hexafluoridophosphate) Meng et al (2008c) 10.1107/S1600536807066512 RISRIV Bis[N-(8-quinolyl)pyridine-2-carboxamidato-3 N,N 0 ,N 00 ]manganese(III) perchlorate monohydrate Meng et al (2008d) 10.1107/S1600536808000287 GISLEA Diaquabis(pyridine-2-carboxylato-2 N,O)cobalt(II) Huang (2008) 10.1107/S1600536808010507 WIZPOL Tetra--2,5-difluorobenzoato-bis[(2,2 0 -bipyridine)(2,5-difluorobenzoato)gadolinium(III)] 10.1107/S1600536808023507 et al (2008) 10.1107/S1600536808028389 NOHYUF catena-Poly[[aqua(2,2 0 -bipyridyl)cobalt(II)]--5-nitroisophthlalato] Liu et al (2008) 10.1107/S1600536808038178 AFIREN Diaquabis(pyridine-2-carboxylato-2 N,O)iron(II) Xia & Sun (2009) 10.1107/S1600536809005765…”

Bis[N-(8-quinolyl)pyridine-2-carboxamidato-κ3N,N′,N′′]manganese(III) perchlorate monohydrate

“…catena-Poly [[bis(1H-benzimidazole-N 3 )palladium(II)]--benzene-1,4-dicarboxylato-2 O 1 :O 4 ] Meng et al (2008b) 10.1107/S1600536807065051 XISCAE Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate Meng et al (2008e) 10.1107/S1600536807065361 SISWIB -Oxido-bis{chlorido[tris(2-pyridylmethyl)amine]manganese(III)} bis(hexafluoridophosphate) Meng et al (2008c) 10.1107/S1600536807066512 RISRIV Bis [N-(8-quinolyl)pyridine-2-carboxamidato-3 N,N 0 ,N 00 ]manganese(III) perchlorate monohydrate Meng et al (2008d) 10.1107/S1600536808000287 GISLEA Diaquabis(pyridine-2-carboxylato-2 N,O)cobalt(II) Huang (2008) 10.1107/S1600536808010507 WIZPOL Tetra--2,5-difluorobenzoato-bis[(2,2 0 -bipyridine)(2,5-difluorobenzoato)gadolinium(III)]…”