Oxidation and reduction of 2,2-bis(diethylamino)-2-ethylium-1-dithioate

Otani, Takashi; Sugihara, Yoshiaki; Ishii, Akihiko; Nakayama, Juzo

doi:10.1002/(sici)1098-1071(1998)9:7<703::aid-hc17>3.0.co;2-9

Cited by 10 publications

(1 citation statement)

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“…Complexes of diaminocarbenium-dithiocarboxylates with various metals, which include Mo, [218] W, [219] Re, [220] Ni, [221] Pd, [222] Pt, [222,223] Ag, [222] and Au, [222] have been reported. Various reactions of the dithiocarboxylate group have been studied, such as cycloaddition with alkynes, [212c] bromination and iodination, [213a] alkylation, [215a,224] oxidation [225] and reduction, [224,226] addition of Grignard and organolithium reagents, [227] and formal addition of tosyl ni-Scheme 29. Betaines derived from diaminocarbenes and CS 2 or CSe 2 trene.…”

Section: Betainesmentioning

confidence: 99%

Carbene Complexes of Nonmetals

Kirmse

2005

Eur J Org Chem

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Electrophilic carbenes accept a variety of n‐ and π‐donors. The products range from persistent ylides to matrix‐isolated xenon complexes. Ylides can be viewed as carbene complexes if they regenerate carbenes thermally or undergo concerted methylene transfer reactions. According to these definitions, the present review focuses on oxonium and iodonium ylides. Transient π‐complexes appear to be involved in addition reactions of carbenes with arenes (but not with alkenes). Nucleophilic carbenes form adducts with Lewis acids which are, for the most part, stable and have been well characterized structurally. Only recently attention has been directed to reversible systems. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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Section: Betainesmentioning

confidence: 99%