Aluminum–plastic
multilayer films have been widely used
in the packaging industry, but the recycling of such a material is
a great challenging task. Herein, we reported a facile route to produce
value-added composites with high thermal conductivity and high electrical
insulation from aluminum–plastic package waste (APPW) for the
first time. Briefly, solid-state shear milling (S3M) technology was
applied to prepare ultrafine APPW powder and exfoliate expandable
graphite (EG) into graphite nanoplatelets (GNPs) with a lateral dimension
of 1–5 μm which constructed the conductive network. For
the blocking of electron transfer through the aluminum/GNPs network
in composites, an in situ oxidation process was employed for aluminum
flakes to form a nano-Al2O3 electronic insulation
layer around the aluminum flakes, whereas phonons can transport through
this barrier layer easily. As a result, the APPW/GNPs composites exhibit
an excellent balance of thermal conductivity and electrical insulation,
well above all reported data to date on graphite or graphene/polymer
composites, with a thermal conductivity of 1.7 W/(m K) and electrical
conductivity of 10–10 S/cm. Furthermore, enhanced
mechanical strength and stiffness are achieved in APPW/GNPs composites.
Such materials could have potential applications in the electronic
industry and turn an environmental pollutant into a valuable resource.