Oxidation of 1,2‐Bis(cyanoalkyl)hydrazines to Azobisnitriles Using Trichloroisocyanuric Acid.

Abstract

Nitriles P 0350Oxidation of 1,2-Bis(cyanoalkyl)hydrazines to Azobisnitriles Using Trichloroisocyanuric Acid. -Trichloroisocyanuric acid is found to efficiently oxidize disubstituted hydrazines (I) to the corresponding diazonitrile-compounds (II) under mild conditions and in excellent yields. -(MOHITE, S. A.; DESAI*, U. V.; PORE, D. M.; MANE, R. B.; WADGAONKAR, P. P.; J. Chem. Res. 2004, 9, 645-646; Dep. Chem., Shivaji Univ., Kolhapur 416 004, India; Eng.) -C. Oppel