Oxidation of 1-Octene by the Molecular Oxygen in the Presence of Immobilized Catalytic Compositions

Abstract

The influence of immobilized catalytic compositions, obtained by immobilization of cyanide complexes of transition metals: Ni, Pd, Pt, Со, Fe, Ru, and oxysalts of vanadium on the aluminum oxide as a carrier, on the initial stages of the liquid-phase oxidation reaction of 1-octene by the molecular oxygen was studied. It was established that the highest activity in the oxidation reaction of 1-octene by the molecular oxygen showed the catalytic composition containing immobilized ruthenium cyanide complex K 2 [Ru(CN) 6 ]-MnCl 2 •4H 2 O (XI) whereas the activity of catalytic composition containing immobilized nicole cyanide complex K 2 [Ni(CN) 4 ]-VO(SO 4)•3H 2 O (I) was the lowest one.