2008
DOI: 10.1590/s0103-50532008000800007
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Oxidation of mono-phenols to para-benzoquinones: a comparative study

Abstract: A oxidação de mono-fenóis à para-benzoquinonas é assunto de interesse contínuo devido à existência de inúmeros produtos naturais contendo esta unidade estrutural. As para-benzoquinonas possuem reatividade química importante como agentes oxidantes e como dienófilos na reação de Diels-Alder. Usualmente nós preparamos as para-benzoquinonas pela reação de oxidação dos respectivos mono-fenóis com oxigênio molecular e catalisada por [Co II (salen)]. Porém, foi necessário estudar estas oxidações utilizando-se outros … Show more

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Cited by 32 publications
(32 citation statements)
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“…The ethereal solution was dried over anhydrous MgSO 4 and the solvent evaporated. The residue was usually purified by sublimation (or by flash column chromatography when necessary, using as eluent a mixture of 9:1 hexane/ethyl acetate) (Dockal et al 1985;Uliana et al 2008).…”
Section: Methodsmentioning
confidence: 99%
“…The ethereal solution was dried over anhydrous MgSO 4 and the solvent evaporated. The residue was usually purified by sublimation (or by flash column chromatography when necessary, using as eluent a mixture of 9:1 hexane/ethyl acetate) (Dockal et al 1985;Uliana et al 2008).…”
Section: Methodsmentioning
confidence: 99%
“…Simple mortar and pestle mixture of a cheap grade of FeCl 3 and Aerosil ® silica produces the catalyst. All the reactions were tested first without FeCl 3 , or the silica, or the catalyst mixture, and then with 4% and 10% mol equivs.…”
Section: Methodsmentioning
confidence: 99%
“…memiliki kandungan antioksidan fenol dan flavonoid yang lebih tinggi dibandingkan dengan sampel kering, hal tersebut diduga disebabkan senyawa polifenol pada umumnya rentan terhadap oksidasi yang menyebabkan penurunan jumlah setelah pengeringan. Floroglusinol merupakan struktur dasar dari florotanin seperti fenol pada umumnya dapat teroksidasi menjadi senyawa benzokuinon (Uliana et al 2008).…”
Section: Aktivitas Antioksidanunclassified