Oxidation of olefins catalyzed by Iron (III) complexes of bis-benzimidazolyl diamide ligands

Ahuja, Gauri; Kumar, Ravinder; Mathur, Pavan

doi:10.1016/j.molstruc.2011.12.047

Cited by 6 publications

(1 citation statement)

References 37 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Due to d 9 configuration of copper(II) a broad but a much less intense d-d band is observed at 640 nm [43] (Figure 2). The IR spectra of the copper complex has characteristic IR band at 1619 cm −1 due to ν (C=N) indicating a coordination of azomethine nitrogen and imine nitrogen to the copper [48][49][50][51][52][53] . The band between 1419 cm −1 and 742 cm −1 is assigned to ν(C=N-C=N) stretching of the benzimidazole group [54] .…”

Section: Electronic Spectroscopy and Ir Studiesmentioning

confidence: 99%

Morphology based catalytic oxidation of phenylpropyne into 1,2-diketones, aldehyde and acid using Cu(II) complex

Kaushik,

Malik,

Tevatia

et al. 2023

Appl. Chem. Eng.

View full text Add to dashboard Cite

Aldehyde, 1,2-diketones, and acid were prepared by copper-catalyzed oxidation of phenyl propyne, using t-BuOOH as the oxidant, heterogeneously. Aldehyde is formed as a major product under neutral conditions. Under mild conditions, catalysis was carried out using catalytic amounts of [Cu(L)Br] with N-methyl benzimidazolyl Schiff base ligand and stoichiometric amounts of oxidant in CH3CN. The several properties of the catalyst were characterized by using UV-Vis, FT-IR, PXRD, CV, and Electron paramagnetic resonance techniques. Comparative SEM measurement of catalyst before and after the catalysis shows that the morphology and size of rods affect the catalytic efficiency. The percentage yields of products were determined by GC-MS.

show abstract