Oxidation of Sulfides with H2O2 Catalyzed by Impregnated Graphene Oxide with Co–Cu–Zn Doped Fe3O4/Co3O4–MoO3 Nanocomposite in Acetonitrile

Khoshroo, M R; Hosseini‐Monfared, Hassan

doi:10.1007/s10904-016-0459-7

Cited by 8 publications

(2 citation statements)

References 75 publications

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“…The MoO bond stretching mode causes the peak at 996 cm –1 . The stretching mode of the MoOMo bonds and the asymmetric stretching mode of the O-Mo-O bonds in α-MoO 3 are responsible for the peaks at 867 and 694 cm –1 , respectively . Moreover, the pore structure evolution of P-MoO 3 and Co-MoO 3– x is examined using nitrogen adsorption–desorption measurements, as shown in Figure e.…”

Section: Resultsmentioning

confidence: 99%

“…20,21 The Raman spectra of P-MoO 3 and Co-MoO 3−x show three bands located at 663 cm −1 (B 2g /B 3g , v as , O-Mo-O stretch), 816 cm −1 (A g , v s , Mo�O stretch), and 993 cm −1 (A g , v as , Mo�O stretch), 22 MoO 3 are responsible for the peaks at 867 and 694 cm −1 , respectively. 23 Moreover, the pore structure evolution of P-MoO 3 and Co-MoO 3−x is examined using nitrogen adsorption− desorption measurements, as shown in Figure 2e. The samples have hierarchically porous structures.…”

Section: Resultsmentioning

confidence: 99%

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Revealing Interstitial Diffusion and Vacancy Diffusion Kinetics of Battery-like Electrodes for High-Performance Pseudocapacitors

Yin

Hao

2023

ACS Appl. Energy Mater.

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Battery-type materials have been identified as highly promising electrode materials for supercapacitors due to their high theoretical capacitance. However, their substantially lower practical capacitance is due to their poor electrode kinetics, which severely restrict the usage of redox-active regions on the electrode surface. To address this issue, the oxygen-vacancy-abundant Co-MoO 3−x microsphere structure is used as a representative example to explore the interstitial diffusion and vacancy diffusion kinetics by adjusting the internal crystal structure, ultimately achieving an accelerated H + ion transport rate. First-principles simulations show that the defect structure in Co-MoO 3−x , which originates from Co 3d orbitals and is generated close to the Fermi level, can modulate the electronic states. The prepared asymmetric supercapacitor device using Co-MoO 3−x exhibits a very high specific capacitance of 167.7 C/g at 1 A/g, a high energy density of 30.2 Wh/kg at a power density of 865 W/kg, and an excellent capacitance retention of 82.1% after 5000 cycles in H 2 SO 4 electrolyte. This research demonstrates the potential for internal crystal structure adjustment to enhance the performance of electrode materials, especially battery-like electrode materials, for high-performance supercapacitors.

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Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Revealing Interstitial Diffusion and Vacancy Diffusion Kinetics of Battery-like Electrodes for High-Performance Pseudocapacitors

Yin

Hao

2023

ACS Appl. Energy Mater.

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Oxygenation of sulfides catalysed by SBA‐15‐immobilized molybdenum(VI) complex of a bis(phenol) diamine ligand using aqueous hydrogen peroxide as a green oxidant

Saberikia

Safaei

Karimi

et al. 2018

Applied Organom Chemis

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A highly efficient and reusable molybdenum-based catalyst has been synthesized by covalent grafting of a bis(phenol) diamine ligand, namely 2-(((2-bromoethyl) (2-((3,5-di-tert-butyl-2-hydroxybenzyl)amino)ethyl)amino)methyl)-4,6-di-tertbutylphenol, onto functionalized ordered mesoporous silica (SBA-15) followed by complexation with MoO 2 (acac) 2 . The resulting organic-inorganic hybrid material was found to be a highly effective catalyst for oxygenation of various sulfides to their corresponding sulfoxides or sulfones. The catalyst was characterized using transmission and scanning electron microscopies, X-ray photoelectron, Fourier transform infrared and atomic absorption spectroscopies, Brunauer-Emmett-Teller surface area analysis and thermogravimetric analysis.Mild reaction conditions, high selectivity and easy recovery and reusability of the catalyst render the presented protocol very useful for addressing industrial needs and environmental concerns.

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Chirally-Modified Graphite Oxide as Chirality Inducing Support for Asymmetric Epoxidation of Olefins with Grafted Manganese Porphyrin

et al. 2019

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Oxidation of Sulfides with H2O2 Catalyzed by Impregnated Graphene Oxide with Co–Cu–Zn Doped Fe3O4/Co3O4–MoO3 Nanocomposite in Acetonitrile

Cited by 8 publications

References 75 publications

Revealing Interstitial Diffusion and Vacancy Diffusion Kinetics of Battery-like Electrodes for High-Performance Pseudocapacitors

Revealing Interstitial Diffusion and Vacancy Diffusion Kinetics of Battery-like Electrodes for High-Performance Pseudocapacitors

Oxygenation of sulfides catalysed by SBA‐15‐immobilized molybdenum(VI) complex of a bis(phenol) diamine ligand using aqueous hydrogen peroxide as a green oxidant

Chirally-Modified Graphite Oxide as Chirality Inducing Support for Asymmetric Epoxidation of Olefins with Grafted Manganese Porphyrin

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