2005
DOI: 10.1007/s11176-005-0253-7
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Oxidation State of Cobalt in the Coordination Compounds with N-(Thio)phosphorylated Acylamidophosphinates in Solutions

Abstract: Acylamidophosphates and their thio analogs of the general formula RC(X)NHP(Y)R`2 form fairly stable chelates with a series of double-charged metal ions, in particular, with Co(II) ions [1,2]. The presence of coordination-active (thio)carbonyl and (thio)phosphoryl groups and of a relatively acidic proton in the molecules of N-(thio)phosphorylated (thio)ureas and (thio)amides predetermines the possibility of chelating coordination of these ligands through the sulfur and oxygen donor centers with the formation of… Show more

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“…It is known that N-(thio)phosphorylated (thio)ureas and (thio)amides RC(X)NHP(Y)(OR ) 2 (X, Y = O, S) in aqueous alcohol medium are weak acids and easily deprotonated under the influence of bases [1][2][3]. The negative charge is delocalized in the X-C-N-P-Y backbone and can be described by …”
Section: Introductionmentioning
confidence: 99%
“…It is known that N-(thio)phosphorylated (thio)ureas and (thio)amides RC(X)NHP(Y)(OR ) 2 (X, Y = O, S) in aqueous alcohol medium are weak acids and easily deprotonated under the influence of bases [1][2][3]. The negative charge is delocalized in the X-C-N-P-Y backbone and can be described by …”
Section: Introductionmentioning
confidence: 99%