1975
DOI: 10.1002/srin.197503621
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Oxidation von festem Eisen durch einen Film von flüssigem Eisenoxid

Abstract: Oxidation von Eisenkugeln bei 1450 °C in Stickstoff‐Sauerstoff‐ oder Helium‐Sauerstoff‐Gemischen. Steuerung der Oxidationsgeschwindigkeit durch konvektive Diffusion in der Gasphase. Messung der Erwärmung der Probe durch die bei der Oxidation frei werdende Reaktionswärme.

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“…All the authors assume that the increase of scale thickness is controlled by solid state diffusion and occurs, correspondingly, according to the parabolic rate law [1][2][3][4][5][6][7]. But this is not so .. At thin oxide layer the scale growth is controlled by transport of oxygen through a gaseous boundary layer or/and by a slow surface reaction [8][9][10]. In these cases the rate law is linear.…”
mentioning
confidence: 99%
“…All the authors assume that the increase of scale thickness is controlled by solid state diffusion and occurs, correspondingly, according to the parabolic rate law [1][2][3][4][5][6][7]. But this is not so .. At thin oxide layer the scale growth is controlled by transport of oxygen through a gaseous boundary layer or/and by a slow surface reaction [8][9][10]. In these cases the rate law is linear.…”
mentioning
confidence: 99%