Oxidations and Dehydrogenations with N-Bromosuccinimide and Related N-Haloimides.

Mechanistic Aspect of Iridium(III) Catalyzed Oxidation of Ethylene Glycol by Chloramine-T in Aqueous Acidic Medium: A Kinetic Model

“…Depending upon the pH of the medium, it forms various oxidizing species and thus shows a variety of kinetic results [6][7][8][9]. Several researchers have studied the oxidizing behavior of CAT [10][11][12][13]and numerous studies focus on the mechanistic aspects of the redox reactions in acidic media. In most of the studies one of the species, RNHCl (R = CH 3 C 6 H 4 SO 2 ), HOCl, or H 2 OCl + , has been considered as the reactive species [14].…”

Synergistic Effect of [Ru(III) + Ir(III)] in N-Bromosuccinimide Reaction with Certain Aliphatic Ketones: A Kinetic Study

“…N-bromosuccinimide (NBS) has been used as a versatile oxidizing agent and analytical reagent in acid and alkaline media [11][12][13][14][15][16][17][18][19][20][21][22][23][24]. In recent past microconcentrations (10 −6 to 10 −5 M) of Ru(III) and Ir(III) have been employed as an efficient catalyst in N-bromosuccinimide (NBS) oxidations and other redox systems [25][26][27][28][29][30][31].…”

Mono and dibromo-5,5-diethylbarbituric acids for cleavage of trimethylsilyl ethers

“…NBromo compounds are widely applicable in industrial processes for the synthesis of drugs, pharmaceuticals and agrochemicals. 1 These materials have also been used as brominating and oxidative agents and can catalyze many organic reactions via in-situ generation of Br + . 2 Effective methods for protection and deprotection of functional groups play a major role in the total synthesis of natural products.…”