Oxidative dehydrogenation of 5-(pyridine-2-yl-methyl)-2-thioxo-4-imidazolidinones in complexation reaction with copper(II) chloride

Majouga, Alexander G.; Белоглазкина, Е. К.; Yudina, Anna; Миронов, А. В.; Зык, Н. В.

doi:10.1016/j.inoche.2014.11.021

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Cited by 10 publications

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“…The bond length of Cu-Cl ranges from 2.2510(7) to 2.2771(6) Å with an average value of 2.264(7) Å, which is normal and similar to the counterparts found in the literature. [17][18][19][20][21] For the requirement of charge balance, 2,2'-dimethyl-2,2'-bipyridinium moieties must be protonated at the nitrogen atoms. The bond angle of Cl-Cu-Cl is in a range of 95.42(2)°-140.78(4)°.…”

Section: Crystal Structurementioning

confidence: 99%

In situ syntheses and characterization of two phases of a copper complex: structural difference leading to different properties

Yi¹,

Fang²,

Zhou³

et al. 2019

Rev.Roum.Chim.

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A copper complex possessing two phases, i.e. α phase 2,2'-dimethyl-2,2'bipyridinium tetrachloro-copper(ii) α-CuCl 4 (N,N'-dimethyl-2,2'-H 2 bipy) (1) and β phase 2,2'-dimethyl-2,2'-bipyridinium tetrachloro-copper(ii) β-CuCl 4 (N,N'-dimethyl-2,2'-H 2 bipy) (2) has been synthesized via solvothermal reactions and structurally characterized by single-crystal X-ray diffraction. Complex 1 crystallizes in the space group C2/c of the monoclinic system with four formula units in a cell:

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