Oxidative nitration of mononitroalkanes in a system sodium nitrite-polyhaloalkane

Synthesis of 3,4,5‐Trisubstituted Isoxazoles from Morita–Baylis–Hillman Acetates by an NaNO2/I2‐Mediated Domino Reaction

“…The authors inadvertently omitted citing two seminal publications [1,2] pertaining to oxidative nitration of nitroalkanes which were brought to their notice by an attentive reader. The authors inadvertently omitted citing two seminal publications [1,2] pertaining to oxidative nitration of nitroalkanes which were brought to their notice by an attentive reader.…”

Corrigendum: Synthesis of 3,4,5‐Trisubstituted Isoxazoles from Morita–Baylis–Hillman Acetates by an NaNO2/I2‐Mediated Domino Reaction

“…In this Communication, the statement “analogous nucleophilic addition on the C−H bond α to the nitro group is unprecedented” (page 10927, first paragraph, line 6–7) must be retracted. The authors inadvertently omitted citing two seminal publications pertaining to oxidative nitration of nitroalkanes which were brought to their notice by an attentive reader.…”

“…The authors inadvertently omitted citing two seminal publications [1,2] pertaining to oxidative nitration of nitroalkanes which were brought to their notice by an attentive reader. In view of these publications, an alternate mechanism which appears to be more logical towards explaining the formation of the observed product is suggested (Scheme 3).…”

Berichtigung: Synthesis of 3,4,5‐Trisubstituted Isoxazoles from Morita–Baylis–Hillman Acetates by an NaNO2/I2‐Mediated Domino Reaction

“…In dieser Zuschrift muss die Behauptung "analogous nucleophilic addition on the CÀH bond a to the nitro group is unprecedented" (S. 11077,erster Absatz, Zeile 6-7) zurückgezogen werden, nachdem die Autoren durch einen aufmerksamen Leser auf zwei vorhergehende Verçffentlichungen [1,2] zur oxidativen Nitrierung von Nitroalkanen hingewiesen wurden. In Anbetracht dieser Verçffentlichungen wird ein alternativer Mechanismus vorgeschlagen, der die Bildung der beobachteten Produkte auf logischere Weise zu erklären scheint (Schema 3).…”