The collections of ambient fine particles were carried out in the period of January 16 to 31, 2013, in Beijing. The levels of carbonaceous aerosols (i.e., organic carbon and elemental carbon) in fine particles were determined. The chemical compositions of primary source tracers including alkanes, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(e)pyrene, benzo(ghi)perylene, picene, 17a(H)-22,29,30-trisnorhopane, levoglucosan, Al and Fe in fine particles were analyzed. Chemical mass balance (CMB) model coupled with inorganic and organic source tracers was utilized to estimate daily contributions of primary sources (e.g., coal combustion, biomass burning, dust source, mobile source) to organic carbon (OC). The sensitivity analysis of specific primary source was carried out in order to obtain the accurate contribution from primary sources. Our study indicated that CMB with inorganic and organic source tracer method was efficient for apportioning primary sources of OC in Beijing during high air pollution episodes.