Oxide-phosphate layers with zirconium compounds on titanium

Structure and corrosion resistance of ZrO2 ceramic coatings on AZ91D Mg alloys by plasma electrolytic oxidation

“…et al for the first time reported the preparation of ZrO 2 coatings on Al alloys in K 2 ZrF 6 solution in 1996 [17][18][19][20][21]. Except adding dispersed ZrO 2 or Zr(OH) 4 particles in the other electrolytes [22][23][24] or adopting Zr(SO 4 ) 2 electrolyte directly [19], fluorozirconate electrolyte is the most often adopted one to prepare ZrO 2 ceramic coating up to now [25][26][27][28][29].…”

Oxidative Inorganic Multilayers for Polypyrrole Film Generation

“…Poly(metaphosphates), with the general formula [MPO 3 ] n , where M is a metal ion or hydrogen, have been known for a long time,8 but, to our knowledge, they have not been used for the LbL assembly. Thin films from similar components have been prepared with plasma‐electrolytic oxidation 9. Furthermore, different types of well‐ordered phosphate‐metal multilayers have been prepared using zirconium(IV) and small organic bisphosphonates 10.…”

“…Thin films from similar components have been prepared with plasma-electrolytic oxidation. [9] Furthermore, different types of well-ordered phosphate-metal multilayers have been prepared using zirconium(IV) and small organic bisphosphonates. [10] Polyphosphates are capable of complexing various metal ions and have many vital functions in living cells [11] In this paper, we demonstrate that the metal ions are not only the building blocks of the multilayer assembly but may also incorporate their specific activity into the multilayer.…”