2015
DOI: 10.7598/cst2015.998
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Oxidorhenium(V) and Imidorhenium(V) Complexes of Pyridylpyridazine:Oxygen Atom Transfer, Oxidation and Substitution Involving Oxido, Phosphine Oxide and Phosphine Coordination

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Cited by 2 publications
(6 citation statements)
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“…A characteristic Re-O stretch of the ReO 4 anion in 6 occurs near 904 cm -1 . The complexes of the type 2-4 have magnetic moment near 2 µB as in several other rhenium(III) species 4,6,7,8,11 . All the complexes display paramagnetically shifted 1 H NMR lines.…”
Section: Spectramentioning
confidence: 88%
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“…A characteristic Re-O stretch of the ReO 4 anion in 6 occurs near 904 cm -1 . The complexes of the type 2-4 have magnetic moment near 2 µB as in several other rhenium(III) species 4,6,7,8,11 . All the complexes display paramagnetically shifted 1 H NMR lines.…”
Section: Spectramentioning
confidence: 88%
“…Re(OPPh 2 (CH 2 )PPh 2 )Cl 3 (dppz) [Re IV (OPPh 2 (CH 2 )PPh 2 )Cl 3 (dppz)]ReO 4 (6) It is unclear how the ReO 4 anion originated from the starting material but this has precedence in rhenium chemistry 6,8,9 .…”
Section: Methodsmentioning
confidence: 99%
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“…Up to my knowledge, this is the first example of d 2 mono oxo complex with nucleophilic properties. To gain further insight into the details mechanism and the nature of the intermediate that involved in the catalytic process of the metal oxo complexes, computational studies on these complexes have been performed and attracted the scientific attention [23][24][25][26][27][28]. The general function of oxomolybdenum enzymes is catalysis of oxygen transfer reaction through the catalytic cycle between Mo(VI)O 2 and Mo(IV)=O [1,29].…”
Section: Introductionmentioning
confidence: 99%