Oxime ligands for Pd catalysis of the Mizoroki–Heck reaction, Suzuki–Miyaura coupling & annulation reactions

New class of RSO2-NHC ligands and Pd/RSO2-NHC complexes with tailored electronic properties and high performance in catalytic C–C and C–N bonds formation

“…49 °C. 87 ). The physical and spectral characteristics were identical to the sample of compound 12 prepared by the procedure described in the literature.…”

“…The physical and spectral characteristics were identical to the sample of compound 12 prepared by the procedure described in the literature. 87 4.9. Catalytic trials of complexes 3a and 3e and (IPr)PdCl 2 Py in the Buchwald-Hartwig cross-coupling Under an argon atmosphere, a screw-capped glass tube equipped with a magnetic stir bar was charged with sodium tert-butoxide (72 mg, 0.75 mmol) and sealed with a screw cap fitted with a septum.…”

High performance supercapacitive behaviors of oximes in a poly(aniline-co-pyrrole) based conducting polymer structure

“…[67][68][69] Oximes, vic-dioximes, and their metal complexes have attracted enormous interest from research groups worldwide because they are easily synthesizable by many different methods and their physical and chemical properties are devisable according to their application areas by using different substituents and metal salts. 68,70 These compounds have been employed in many fields of science with many application areas such as catalysis, 71,72 nanoparticles, 73,74 electrochemical sensors, [75][76][77] anti-chemical warfare agents, 76,78 anti-cancer [79][80][81] and anti-bacterial treatments. [82][83][84] Despite the wide usage of oximes in different areas, any notable studies had been working on in the field of energy storage about their properties.…”

Bis(oxime Palladacyle) Supported on Magnetized SBA-15 as an Efficient and Retriveble Catalyst for the Mizoroki-Heck Reaction

“…Oxime-palladacycles are members of the mentioned family, which were obtained by ortho-metalation of oximes in 1970 [10]. These complexes exhibited enhanced activity in C-C bond formation reactions such as Mizoroki-Heck [11], Stille [12], Suzuki-Miyaura [13], Kumada [12], Hiyama [14], Ullmann [15], Sonogashira [16], and Glaser-type coupling [16], compared to Pd(OAc) 2 or other Pd salts [17].…”

“…Palladacycles also catalyze carbonylations [18], annulations [11], arylation of allyl alcohols [19], C-H activation [20], oxime rearrangements [21], and behave as metalloenzymes in hydrolytic processes [17]. Palladacycles usually contain a very low amount the expensive palladium that is cost-effective.…”