The energy spectra of electrons detached from O-and S ions by 488.0nm and 514.5 nm photons have been measured with high electron energy resolution (5 meV) in order to determine the branching ratios for the various 2P3/2.1/2 --" aP2, 1.o fine-structure transitions together with their respective angular distributions. Detailed information on the relative importance of the s-and d-wave continuum is obtained.