1987
DOI: 10.1103/physrevb.36.3608
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Oxygen ordering and the orthorhombic-to-tetragonal phase transition inYBa2Cu3

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Cited by 1,149 publications
(155 citation statements)
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“…This fact has led most of the proposed microscopic theories to assume a CuO 2 square planar structure. However, for the practical reason of sample quality, some of the most important and defining experiments have been performed on YBa 2 Cu 3 O 7−δ (Y123), which does not have a square lattice, but rather an orthorhombic structure (b/a ≈ 1.015), caused by the presence of a CuO chain layer [1]. This orthorhombicity, according to LDA calculation [2], should result in significant anisotropy in the in-plane electronic structure (this term will be used throughout this paper to refer to the electronic states associated with the CuO 2 plane), making it problematic to compare theories based on a square lattice with experimental data from Y123.…”
mentioning
confidence: 99%
“…This fact has led most of the proposed microscopic theories to assume a CuO 2 square planar structure. However, for the practical reason of sample quality, some of the most important and defining experiments have been performed on YBa 2 Cu 3 O 7−δ (Y123), which does not have a square lattice, but rather an orthorhombic structure (b/a ≈ 1.015), caused by the presence of a CuO chain layer [1]. This orthorhombicity, according to LDA calculation [2], should result in significant anisotropy in the in-plane electronic structure (this term will be used throughout this paper to refer to the electronic states associated with the CuO 2 plane), making it problematic to compare theories based on a square lattice with experimental data from Y123.…”
mentioning
confidence: 99%
“…In Fig. 6 we have transformed the a, b lattice parameters of YBCO from different authors [5,6,22,23] into the shear angle c~--90 ~ which permits comparison with other ferroelastics [24]. It is noteworthy that shear angles as small as 3 min of arc (Fe3BTO13I) or 10 min of arc (Gd2(MoO4)3) can lead to cracking if mutually perpendicular walls meet.…”
Section: ~176mentioning
confidence: 99%
“…the symmetry operations to transform one domain into all others -are given by the symmetry elements lost during the transition. However, the tetragonal-,orthorhombic phase transition of YBazCU3OT_0, occurring at about 700 ~ at ~ 1 bar of oxygen [5], has to some extent a destructive character because it is linked with a chemical reaction involving oxygen loss~ absorption:…”
Section: Introductionmentioning
confidence: 99%
“…The Cu(2)(Cu0 2 ) layers adjacent to the Y atoms show a "dimpled" form. By neutron powder diffraction experiments [9,10] it was shown that in the low temperature phase the oxygen vacancies in the Cu(l)layers are ordered and located in j00 sites. Thus, Cu-0 chains are remaining along the b axis.…”
Section: Structures and Microstructuresmentioning
confidence: 99%