2024
DOI: 10.1016/j.cej.2023.147775
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Oxygen vacancy-regulated atomic dispersed Au on CeFeO for preferential oxidation of CO in H2-rich stream

Ganghua Xiang,
Hao Chen,
Chengfeng Yi
et al.
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Cited by 12 publications
(2 citation statements)
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“…17 After loading Pd, the F 2g peaks of Pd/CeO 2 and Pd/CeO 2 @SiO 2 were red-shifted, with peaks appearing at 461cm −1 and 453 cm −1 , respectively, which can be explained by the entry of Pd into the CeO 2 lattice and the creation of ˙oxygen vacancies in CeO 2 . 18,19 In addition, a small peak (D) induced by CeO 2 defects at around 599 cm −1 could be found in CeO 2 , Pd/CeO 2 and Pd/CeO 2 @SiO 2 . The peak intensity of the D peak depended on the presence of certain defects and was enhanced when oxygen vacancies were present in CeO 2 .…”
Section: Resultsmentioning
confidence: 94%
“…17 After loading Pd, the F 2g peaks of Pd/CeO 2 and Pd/CeO 2 @SiO 2 were red-shifted, with peaks appearing at 461cm −1 and 453 cm −1 , respectively, which can be explained by the entry of Pd into the CeO 2 lattice and the creation of ˙oxygen vacancies in CeO 2 . 18,19 In addition, a small peak (D) induced by CeO 2 defects at around 599 cm −1 could be found in CeO 2 , Pd/CeO 2 and Pd/CeO 2 @SiO 2 . The peak intensity of the D peak depended on the presence of certain defects and was enhanced when oxygen vacancies were present in CeO 2 .…”
Section: Resultsmentioning
confidence: 94%
“…41 In addition, O v preferentially binds to Au single atoms rather than Au nanoparticles, which enhances the interfacial interaction between TiO 2 and Au single atoms. 51 Therefore, TiO 2 -DBD prepared by the plasma method are rich in oxygen vacancies, facilitating the stable presence of Au in Au 1 /TiO 2 -DBD in the single-atom state. 41,52 As shown in Fig.…”
Section: Resultsmentioning
confidence: 99%