Cite this article as: Noha Hakmeh, Christophe Chlique, Odile MerdrignacConanec, Bo Fan, François Cheviré, Xianghua Zhang, Xianping Fan, Xusheng Qiao, Combustion synthesis and up-conversion luminescence of La 2 O 2 S:Er 3 þ , Yb 3 þ nanophosphors, Journal of Solid State Chemistry, http://dx.
AbstractLa 2 O 2 S:Er 3+ ,Yb 3+ nanocrystalline up-converting phosphors were synthesized by a combustion method at low temperature, using ethanol as pre-ignition fuel and thioacetamide as sulfurizing agent and organic fuel. The phosphors were characterized by powder X-ray diffractometry, scanning electron microscopy, UV/Vis/NIR spectroscopy and fluorescence spectroscopy. Pure and well-crystallized La 2 O 2 S:Er 3+ ,Yb 3+ nanoparticles, of the order of 50-200 nm, are obtained after a post-treatment in a H 2 S/N 2 flow for 2h at 1000°C. The efficient energy transfer from Yb 3+ to Er 3+ results in a strong up-conversion upon excitation at 980 nm. The emission spectra show the intense green emissions corresponding to the ( 2 H 11/2 , 4 S 3/2 ) → 4 I 15/2 transitions and a red emission corresponding to the 4 F 9/2 → 4 I 15/2 transition. Additionally, within the investigated codoping concentrations, no significant concentration quenching effect and back energy transfer from Er 3+ to Yb 3+ were evidenced. This research highlights the influence of the sulfurization treatment on the purity/crystallinity/morphology of the nanocrystals and the luminescence efficiency.