2015
DOI: 10.1016/j.cej.2014.11.072
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Ozone-catalytic oxidation of gaseous benzene over MnO2/ZSM-5 at ambient temperature: Catalytic deactivation and its suppression

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Cited by 85 publications
(28 citation statements)
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“…Predicted rates were obtained by fitting experimental data in Table 1 with Eqs. (8), (9) and (21) for power law, L-H s and L-H d model, respectively. The corresponding parameter estimates were given in Table 2 and 4.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…Predicted rates were obtained by fitting experimental data in Table 1 with Eqs. (8), (9) and (21) for power law, L-H s and L-H d model, respectively. The corresponding parameter estimates were given in Table 2 and 4.…”
Section: Resultsmentioning
confidence: 99%
“…Catalytic ozonation is a promising approach used to degrade VOCs [5][6][7][8][9]. The catalytic ozonation of VOCs is considered a surface reaction, which follows the Langmuir-Hinshelwood mechanism and comprises adsorbed VOC molecules and atomic oxygen species; this process was originally proposed by Oyama et al [10] to investigate the kinetics and mechanism of the catalytic ozonation of acetone over MnO x /SiO 2 by combining in situ Raman spectroscopy with transient kinetics techniques.…”
Section: Introductionmentioning
confidence: 99%
“…This is significant if O 3 can be decomposed and enhance VOC oxidation during its decomposition. Although direct oxidation of VOCs by O 3 alone can hardly proceed, O 3 becomes highly active for VOC oxidation with the assistance of catalysts [24][25][26]. Transition metal oxides are the most studied catalysts for O 3 decomposition, and among these oxides exhibited superior catalytic activity [27,28].…”
Section: Introductionmentioning
confidence: 99%
“…In this study, ZSM-5 was used to support MnO x due to its mesoporous structure and large specific surface area, which is beneficial not only to the dispersion of metal oxides but also to the adsorption of VOCs and ozone [26,29]. The developed MnO x /ZSM-5 combined well with VUV to eliminate O 3 and degrade benzene, a representative toxic VOC.…”
Section: Introductionmentioning
confidence: 99%
“…However, the reaction products of these treatment technologies are also an environmental concern (CO, CO2) [187,[194][195][196][197][198][199].…”
Section: From Volatile Organic Compounds To Chemicalsmentioning
confidence: 99%