2024
DOI: 10.1039/d4cc02202e
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P(v)-bis(amidophenolate) ligand cooperation: stoichiometric CO-bond cleavage in aldehydes and ketones

Simon B. H. Karnbrock,
Christopher Golz,
Manuel Alcarazo

Abstract: The cooperation between a geometrically constrained, highly electrophilic phosphorus(V) center, and an electronically rich tetradentate bis(amidophenolate) ligand enables the cleavage of the C=O bond from typical aldehydes and ketones delivering...

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