2024
DOI: 10.1021/acs.chemrev.3c00875
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P-Stereogenic Phosphorus Ligands in Asymmetric Catalysis

Tsuneo Imamoto

Abstract: Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient synthesis of useful optically active compounds. They are largely categorized into two classes: backbone chirality ligands and P-stereogenic phosphorus ligands. Most of the reported ligands belong to the former class. Privileged ones such as BINAP and DuPhos are frequently employed in a wide range of catalytic asymmetric transformations. In contrast, the latter class of P-stereogenic phosphorus ligands has remained a small f… Show more

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Cited by 16 publications
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References 691 publications
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