Chromophores with optimized second-order optical nonlinearity to optical loss ratios are
synthesized, poled with an electrical field, and coupled into hardened polymer matrixes. Acentric
order, which is necessary for electro-optic activity, is optimized by the consideration of
chromophore−chromophore electrostatic interactions as well as chromophore−poling field
interactions and thermal collisions which randomize chromophore orientations with respect to
the applied field direction. Reactive ion etching and/or multicolor photolithography are used to
fabricate buried channel waveguide structures out of the resulting polymeric electro-optic
materials and to integrate polymeric waveguides with silica optical fibers. Tapered transitions
are developed to minimize coupling (insertion) loss. Both vertical and horizontal integration of
polymeric electro-optic modulator circuitry with semiconductor very large scale integration
circuitry is demonstrated. Modulation to 113 GHz is demonstrated. Polymeric modulators are
relevant to cable television, phased-array radar, ultrafast analogue-to-digital conversion, high-speed optical switching in local area networks, optical beam steering, optical backplane
interconnects for parallel processors, and voltage sensing.