The geochemical multivariate techniques were applied to recognize different geological units and categorized rock types which accompanied by different penalties. Knowing changes and classification of raw materials with macroscopic and microscopic quantification have direct effect on economic and efficiency in a precipitated calcium carbonate plant. Based on lithological changes, the Darian Formation was divided into four rock units based on a total of 492 chip samples collected from the study area. The main aim objective of this study was to classify the rock types in this area using a multivariate analysis combining the R-mode factor analysis and K-Means method. Due to the opposite vector orientation of SiO