Palladium-catalyzed stereoselective hydrostannation of substituted propargyl alcohols with trineophyltin hydride

Faraoni, María Belén; Gerbino, Darío C.; Podestá, Julio C.

doi:10.1016/j.jorganchem.2008.02.015

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ChemInform Abstract: Palladium‐Catalyzed Stereoselective Hydrostannation of Substituted Propargyl Alcohols with Trineophyltin Hydride.

Faraoni¹,

Gerbino²,

Podestá³

2008

ChemInform

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Organo-tin compounds S 4800Palladium-Catalyzed Stereoselective Hydrostannation of Substituted Propargyl Alcohols with Trineophyltin Hydride. -The Pd-catalyzed hydrostannation of propargylic alcohols (I) with the bulky trineophyltin reagent (II) is presented and the influence of substituents on the propargylic alcohol on the stereo-and regioselectivity is studied. In all cases, the addition proceeds syn-selectively, but the regioselectivity is determined by steric bulk of the substituents (rather than electronic effects). -(FARAONI, M. B.; GERBINO, D. C.; PODESTA*, J. C.; J.

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