2008
DOI: 10.1002/ange.200703889
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Palladium‐Catalyzed Stereospecific Substitution of α,β‐Unsaturated γ,δ‐Epoxy Esters by Alcohols with Double Inversion of Configuration: Synthesis of 4‐Alkoxy‐5‐hydroxy‐2‐pentenoates

Abstract: Stereoselective, epoxide-opening reactions have played very important roles in organic synthesis, particularly in the stereoselective synthesis of biologically important target molecules in natural product and pharmaceutical research.[1]Although a variety of regioand stereoselective substitution reactions of epoxides by an S N 2 mechanism have so far been reported, [1] the stereospecific substitution reaction which proceeds with double inversion of configuration, that is, retention of configuration, is only li… Show more

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