Palladium-catalyzed Suzuki–Miyaura cross-coupling of carboxylic–phosphoric anhydrides via C–O bond cleavage

Abstract

A robust palladium-catalyzed Suzuki-Miyaura reaction of carboxylic–phosphoric anhydrides via highly selective C(O)−O bond cleavage under inorganic base-free conditions has been reported. Carboxylic–phosphoric anhydrides, generated through activating carboxylic acids using phosphates...